There is a great SciAm [article on the cognitive science of what makes experts](http://www.sciam.com/article.cfm?id=the-expert-mind). Some gems:
Dutch psychologist Adriaan de Groot, himself a chess master, confirmed this notion in 1938, when he took advantage of the staging of a great international tournament in Holland to compare average and strong players with the world’s leading grandmasters. One way he did so was to ask the players to describe their thoughts as they examined a position taken from a tournament game. He found that although experts–the class just below master–did analyze considerably more possibilities than the very weak players, there was little further increase in analysis as playing strength rose to the master and grandmaster levels. The better players did not examine more possibilities, only better ones
Chess memory was thus shown to be even more specific than it had seemed, being tuned not merely to the game itself but to typical chess positions. These experiments corroborated earlier studies that had demonstrated convincingly that ability in one area tends not to transfer to another. American psychologist Edward Thorndike first noted this lack of transference over a century ago, when he showed that the study of Latin, for instance, did not improve command of English and that geometric proofs do not teach the use of logic in daily life.
Even so, there were difficulties with chunking theory. It could not fully explain some aspects of memory, such as the ability of experts to perform their feats while being distracted (a favorite tactic in the study of memory). K. Anders Ericsson of Florida State University and Charness argued that there must be some other mechanism that enables experts to employ long-term memory as if it, too, were a scratch pad. Says Ericsson: “The mere demonstration that highly skilled players can play at almost their normal strength under blindfold conditions is almost impossible for chunking theory to explain because you have to know the position, then you have to explore it in your memory.”
Ericsson argues that what matters is not experience per se but “effortful study,” which entails continually tackling challenges that lie just beyond one’s competence. That is why it is possible for enthusiasts to spend tens of thousands of hours playing chess or golf or a musical instrument without ever advancing beyond the amateur level and why a properly trained student can overtake them in a relatively short time. It is interesting to note that time spent playing chess, even in tournaments, appears to contribute less than such study to a player’s progress; the main training value of such games is to point up weaknesses for future study.
Although nobody has yet been able to predict who will become a great expert in any field, a notable experiment has shown the possibility of deliberately creating one. L�szl� Polg�r, an educator in Hungary, homeschooled his three daughters in chess, assigning as much as six hours of work a day, producing one international master and two grandmasters–the strongest chess-playing siblings in history. The youngest Polg�r, 30-year-old Judit, is now ranked 14th in the world.